[(Z)-N-Isopropyl-O-methylthiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)
نویسندگان
چکیده
In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol-ecules comprise the asymmetric unit, and these are connected by an aurophilic inter-action [Au⋯Au = 3.1351 (3) Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S-Au-P = 175.31 (5) and 176.45 (5)°] ascribed to an intra-molecular Au⋯O contact in each case [2.974 (4) and 3.027 (4) Å].
منابع مشابه
[O-Ethyl N-(4-nitrophenyl)thiocarbamato-κS](tri-p-tolylphosphine-κP)gold(I)
A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au⋯π contact [Au⋯Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].
متن کامل[(Z)-N-(2-Chlorophenyl)-O-methylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09 (5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au⋯O = 2.959 (4) Å].
متن کامل[(Z)-N-(4-Chlorophenyl)-O-methylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14 (5)°] due to the close approach of the O atom to the Au atom [Au⋯O = 2.882 (3) Å]. Loosely associated dimers are formed in the crystal structure through C-H⋯O inter-actions.
متن کامل[(Z)-O-Isopropyl N-(4-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
The Au atom in the title compound, [Au(C(10)H(11)ClNOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.134 (3) Å].
متن کامل[(Z)-Ethyl N-isopropylthiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)
The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44 (5)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009